UK dangerous-goods rules are largely aligned with ADR.
The source identifies the Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (as amended).
Dangerous goods are divided into 9 broad UN classes, with some subdivisions.
Class 1: explosives; Class 2: gases; Class 3: flammable liquids.
Class 4.1: flammable solids; 4.2: spontaneously combustible; 4.3: dangerous when wet.
Class 5.1: oxidising substances; 5.2: organic peroxides.
Class 6.1: toxics; 6.2: infectious substances.
Class 7: radioactive; Class 8: corrosive; Class 9: miscellaneous dangerous substances; Class 9A: miscellaneous dangerous substances specifically for lithium batteries.
Each substance has a unique 4-digit UN identification number.
Packing Groups: I = high hazard; II = medium hazard; III = low hazard.
The consignor is responsible for classification/identification and for using UN-approved packaging and correct package labels.
6.2 EXEMPTIONS
ADR provides exemptions for small quantities using five transport categories.
Transport Category 0: extremely dangerous substances.
Transport Categories 1, 2 and 3 broadly correspond to Packing Groups I, II and III.
Transport Category 4 covers items considered minimal danger.
Maximum quantity before full regulations apply, as stated in the material: Category 0 = 0; Category 1 = 20 kg/litres; Category 2 = 333 kg/litres; Category 3 = 1,000 kg/litres; Category 4 = unlimited.
Do not confuse these transport-category exemptions with Limited Quantity rules.
6.3 ADR APPROVAL OF VEHICLES AND TANKS
Certain tank vehicles, tank containers and vehicles carrying explosives require examination, approval and certification.
The source's main thresholds include tank vehicles over 1,000 litres and tank containers over 3,000 litres.
Vehicle examination is carried out by DVSA on behalf of DfT.
ADR vehicles for flammable products must meet specific safety standards, including requirements for electrical systems, master switches, heat shields and exhaust systems.
ADR vehicle certificates must be renewed annually after examination at a DVSA test centre.
Tank examinations are carried out by DfT-approved organisations.
Tank inspections can include internal/external condition checks and hydraulic pressure tests.
Tank inspection intervals vary from 1 to 6 years depending on the tank and contents; 6 years is stated as most common.
A leak test must be carried out at least every 3 years.
6.4 DOCUMENTS TO ACCOMPANY THE LOAD
Dangerous-goods transport documents must accompany the load.
They must state the UN number, substance name, hazard class, packing group where applicable, tunnel code where applicable, packages, total quantity and consignor/consignee details.
Consignors and carriers must retain copies for at least 3 months.
Drivers must receive ADR's standard four-page Instructions in Writing covering accident/emergency actions.
Instructions must be in a language readily understood by each crew member.
Drivers must also carry the appropriate ADR Vocational Training Certificate.
6.5 VEHICLE MARKING
Vehicles carrying dangerous goods must be marked unless exempt under the small-load provisions.
Vehicles within the regulations display a plain orange reflectorised plate at the front.
6.5.1 Road Tankers
UK tankers normally display 5-part Hazchem panels on both sides and at the rear.
Panels include an emergency action code, UN number, danger placard, emergency contact number and an optional company logo.
The emergency action code gives emergency services information on treatment methods and protective equipment.
For multi-substance tankers, compartments are marked with the appropriate placards and orange panels showing UN numbers.
6.5.2 Tank Containers
Tank containers are marked like road tankers for UK journeys involving a single substance: Hazchem panels on both sides and the rear.
6.5.3 Carriage in Bulk
Bulk dangerous goods in tippers/skips are generally marked like tankers.
An emergency telephone number is not essential on the Hazchem panel for bulk carriage, according to the source.
6.5.4 Packages
Above the relevant transport-category thresholds, packaged dangerous goods vehicles require plain orange reflectorised panels at the front and rear.
6.6 LIMITED QUANTITIES – VEHICLE MARKING
Most vehicles carrying packaged dangerous goods in Limited Quantities do not need vehicle marking.
If vehicle GVW exceeds 12 tonnes and total dangerous goods mass exceeds 8 tonnes, marking is required.
The vehicle may use plain orange plates for the front/rear or the special ADR Limited Quantities sign for the front/rear.
6.7 ENVIRONMENTALLY HAZARDOUS SUBSTANCES
Road tankers, bulk tippers and similar vehicles carrying ADR environmentally hazardous substances must display the black-and-white environmental hazard placard adjacent to each of the three hazard warning panels.
6.8 EQUIPMENT
All dangerous-goods vehicles: at least 2 kg dry powder/equivalent extinguisher for cab/engine fire.
Vehicles over 7.5 tonnes GVW: additional extinguisher capacity of at least 10 kg, including one extinguisher of at least 6 kg.
Vehicles 3.5–7.5 tonnes: 2 kg cab extinguisher plus at least 6 kg additional capacity.
At least one suitable wheel chock per vehicle plus an additional chock for any trailer.
At least two self-standing warning signs: reflective cones/triangles or independently powered flashing amber lamps.
Suitable eye-rinsing liquid must be carried.
Spill-control equipment may include a drain cover, shovel and collecting container for relevant substances.
Each crew member needs high-visibility clothing and portable non-sparking lighting.
Other required PPE includes gloves and goggles; escape masks may be necessary for toxic substances.
6.9 TRAINING
All staff involved in handling/transporting dangerous goods require appropriate awareness and safety training.
Training covers legislation, hazards, safe procedures and emergency actions; it should be updated periodically and recorded.
When the quantity exceeds the applicable transport-category limit, drivers require specialised training and a Vocational Training Certificate (ADR certificate).
ADR certificates require a DfT-approved course and examinations set on behalf of DfT by the Scottish Qualifications Authority.
Certificates cover tank or packaged carriage and are specific to the relevant dangerous-goods classes.
ADR vocational certificates are valid for a maximum of 5 years and require refresher training/examination for renewal.
6.10 DANGEROUS GOODS SAFETY ADVISERS
Organisations involved in loading, unloading or transporting dangerous goods must appoint a Dangerous Goods Safety Adviser (DGSA).
DGSAs must be suitably qualified and have sufficient time/resources to perform their duties.
DGSA reports must be retained for at least 5 years.
DGSA duties include checking equipment, vehicle suitability, staff training, sub-contractors, emergency procedures, documentation and loading/unloading procedures.
DGSAs advise on identification, characteristics, marking, equipment and PPE.
They prepare annual reports and investigate/report serious dangerous-goods accidents.
DGSA certificates are valid for a maximum of 5 years before further examinations are required.